ChemInform Abstract: A One-Pot Preparation of Cyanamide from Dithiocarbamate Using Molecular Iodine

Autor:	K. V. V. V. Satyanarayana, Latonglila Jamir, Upasana Bora Sinha, Jayashree Nath, Bhisma K. Patel
Rok vydání:	2010
Předmět:	inorganic chemicals chemistry.chemical_classification Aqueous solution Cost effectiveness Chemistry chemistry.chemical_element General Medicine Iodine Flue-gas desulfurization chemistry.chemical_compound Yield (chemistry) Organic chemistry Cyanamide Dithiocarbamate
Zdroj:	ChemInform. 41
ISSN:	1522-2667 0931-7597
Popis:	An efficient one-pot method for the synthesis of cyanamides from dithiocarbamate salts via a double desulfurization strategy using molecular iodine is disclosed. Dithiocarbamates, by the action of iodine yield isothiocyanates in situ, which on treatment with aqueous NH3 give thioureas. The thioureas so generated undergo further oxidative desulfurization with I2 giving corresponding cyanamides in good yields. Environmental benignity, cost effectiveness and high yields are the important attributes of this one pot procedure.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::b467917c00a3313f6e463db3ee7d7904 https://doi.org/10.1002/chin.201009084 Zobrazit plný text záznamu Plný text