Octahedral metal carbonyls
| Autor: | Paul H. Wermer, Charles B. Dobson, Gerard R. Dobson |
|---|---|
| Rok vydání: | 1986 |
| Předmět: | |
| Zdroj: | Journal of Organometallic Chemistry. 311:C47-C50 |
| ISSN: | 0022-328X |
| DOI: | 10.1016/0022-328x(86)80265-0 |
| Popis: | Ring-closure via olefin coordination in coordinatively-unsaturated cis -[(η 1 -pdpp)W(CO) 4 ], (pdpp = CH 2 CH(CH 2 ) 3 P(C 6 H 5 ) 2 , 4-pentenyldiphenylphosphine) produced via pulsed laser flash photolysis of cis -(pip)(η 1 -pdpp)W(CO) 4 (pip = piperidine) in chlorobenzene has been identified unequivocally. Rates and activation parameters for this pathway and for competitive bimolecular interaction of pip at the solvated coordination site have been measured. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
|