Three-Component Spiro Heterocyclization of Pyrrolediones with Malononitrile and Cyclic Enols

Autor: Andrey N. Maslivets, P. S. Silaichev, E. V. Bushmeleva, T. V. Sal’nikova, Maksim V. Dmitriev
Rok vydání: 2018
Předmět:
Zdroj: Russian Journal of Organic Chemistry. 54:564-567
ISSN: 1608-3393
1070-4280
Popis: Ethyl 4,5-dioxo-2-phenyl-4,5-dihydro-1H-pyrrole-3-carboxylates reacted with malononitrile and five-membered cyclic enols, indan-1,3-dione and cyclopentane-1,3-dione to give 1-substituted ethyl 2-amino-3- cyano-2′,5-dioxo-5′-phenyl-1′,2′-dihydro-5H-spiro[indeno[1,2-b]pyran-4,3′-pyrrole]-4′-carboxylates and ethyl 2-amino-3-cyano-2′,5-dioxo-5′-phenyl-1′,2′,6,7-tetrahydro-5H-spiro[cyclopenta[b]pyran-4,3′-pyrrole]-4′-carboxylates, respectively.
Databáze: OpenAIRE