Some reactions of 8,11,11-trimethyl-11-silabenzo[b]naphtho-[2,3-d]thiophen-6-one at the carbonyl group

Autor:	Ryashentseva Margarita A, Viktor A. Tafeenko, A. A. Astakhov, V. M. Polosin
Rok vydání:	1999
Předmět:	chemistry.chemical_compound Aniline Chemistry Organic Chemistry Condensation Molecule Alcohol Spectroscopy Medicinal chemistry Tertiary alcohols Carbonyl group Phenyllithium
Zdroj:	Chemistry of Heterocyclic Compounds. 35:740-745
ISSN:	1573-8353 0009-3122
DOI:	10.1007/bf02251636
Popis:	Reactions of C- and N-nucleophiles at the carbonyl group of 8,11,11-trimethyl-11-silabenzo-[b]naphtho[2,3-d]thiophen-6-one have been studied. PMR Spectroscopy showed that condensation with aniline gives a mixture of the Z- and E- isomers of the corresponding azomethine. Reaction with n-butyl and phenyllithium gave tertiary alcohols, the molecular structure of which was proved using X-ray crystallography.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::b45d347a4c110629f723f2917eb4e349 https://doi.org/10.1007/bf02251636 Zobrazit plný text záznamu Full text from SpringerLink