An Electron Diffraction Investigation of Methyl Formate, Methyl Acetate and Methyl Chloroformate

Autor:	Verner Schomaker, William Shand, John Michael O'Gorman
Rok vydání:	1950
Předmět:	Chemistry Methyl formate Methyl acetate chemistry.chemical_element General Chemistry Resonance (chemistry) Biochemistry Medicinal chemistry Oxygen Catalysis chemistry.chemical_compound Dipole Colloid and Surface Chemistry Electron diffraction Methyl chloroformate Organic chemistry Free rotation
Zdroj:	Journal of the American Chemical Society. 72:4222-4228
ISSN:	1520-5126 0002-7863
DOI:	10.1021/ja01165a110
Popis:	The structures of simple carboxylic esters have received considerable elucidation from studies of dipole moments. This work is summarized and discussed in the fourth and fifth chapters of Wheland's book, "The Theory of Resonance." 'The conclusion from these studies is that simple aliphatic esters do not have free rotation about the carbonyl carbon-ether oxygen bond, but are planar with the configuration I, which we shall call cis.
Databáze:	OpenAIRE
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