Synthesis of Cyclic Metal Containing Phosphorus- Nitrogen Compounds - A Comparison with Metal Containing Siloxanes
| Autor: | Mathias Noltemeyer, Herbert W. Roesky, Feng Quan Liu, R. Hasselbring, P. Olms, Norbert Winkhofer |
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| Rok vydání: | 1993 |
| Předmět: |
010405 organic chemistry
Chemistry Phosphorus Organic Chemistry Inorganic chemistry chemistry.chemical_element 010402 general chemistry 01 natural sciences Biochemistry Nitrogen 0104 chemical sciences Inorganic Chemistry Metal Polymerization visual_art X-ray crystallography visual_art.visual_art_medium Molecule |
| Zdroj: | Phosphorus, Sulfur, and Silicon and the Related Elements. 76:255-260 |
| ISSN: | 1563-5325 1042-6507 |
| DOI: | 10.1080/10426509308032407 |
| Popis: | The preparation and properties of six- and higher- membered metallacyclophosphazenes is described. A new mechanism for the polymerisation of cyclophosphazenes is discussed. The PN unit is isoelectronic to the SIO unit and therefore metal containing siloxanes have been prepared. They function as model compounds for metal oxides on silica surfaces. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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