Rational Synthesis of Dinuclear Mixed-Valence Cu(I)/Cu(II)Carboxylate Derivatives. Steric Influence of Phosphine Ligands on the Structures of the Complexes

Autor:	Joseph H. Reibenspies, Kevin K. Klausmeyer, Donald J. Darensbourg, Bandana Khandelwal, Matthew W. Holtcamp
Rok vydání:	1994
Předmět:	Steric effects Valence (chemistry) Chemistry Stereochemistry chemistry.chemical_element Crystal structure Medicinal chemistry Copper Inorganic Chemistry chemistry.chemical_compound Malonate Molecule Carboxylate Physical and Theoretical Chemistry Phosphine
Zdroj:	Inorganic Chemistry. 33:2036-2040
ISSN:	1520-510X 0020-1669
Popis:	The mixed-valence Cu(I)/Cu(II) complexes (Ph 3 P) 4 Cu I 2 Cu II (O 2 CCH 2 CO 2 ) 2 (1) and (Cy 3 P) 4 Cu I 2 Cu II (O 2 CCH 2 -CO 2 ) 2 (2), have been prepared from the acid-base reaction of Cu II (acac) 2 or Cu II (butyrate) 2 with the respective copper(I) hydrogen dicarboxylate derivative and their solid-state structures determined crystallographically. The Cu(II) center in both derivatives is chelated by two malonate dianions in a squate-planar geometry
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::b429a13814b7e73d2c00667d448e64f4 https://doi.org/10.1021/ic00087a046 Zobrazit plný text záznamu