Stereoselective Synthesis of 1,2-cis-Arabinofuranosides Using a New Titanium Catalyst

Autor:	Shu Kobayashi, Yoshihiro Yokomizo, Masaaki Yamada, Teruaki Mukaiyama, Shinji Suda
Rok vydání:	1992
Předmět:	chemistry.chemical_classification Reaction mechanism Trimethylsilyl Chemistry Glycoside chemistry.chemical_element General Chemistry Catalysis chemistry.chemical_compound Aldose Organic chemistry Stereoselectivity Trifluoromethanesulfonate Titanium
Zdroj:	Chemistry Letters. 21:1401-1404
ISSN:	1348-0715 0366-7022
Popis:	In the presence of catalytic amounts of [1,2-benzenediolato(2-)-O,O′]oxotitanium and trimethylsilyl triflate, 1-O-trimethylsilyl-2,3,5-tri-O-benzyl-D-arabinofuranose stereoselectively reacts with various trimethylsilyl ethers to afford the corresponding 1,2-cis-arabinofuranosides in high yields.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::b426d254d974f11cf024d905c00f824c https://doi.org/10.1246/cl.1992.1401 Zobrazit plný text záznamu