A comparative study of Rh2-catalyzed intermolecular nitrene transfer reactions: mechanism and chemoselectivity

Autor:	Juping Wang, Kangcheng Zheng, Rongxing Xiao, Li Qian, Zijie Lin
Rok vydání:	2022
Předmět:	Catalysis
Zdroj:	Catalysis Science & Technology. 12:3498-3505
ISSN:	2044-4761 2044-4753
DOI:	10.1039/d2cy00155a
Popis:	The intermolecular catalytic mechanisms using Rh2(esp)2 and Rh2(OAc)4 are analogous and their large difference in aziridination-to-amination chemoselectivity stems from the steric effect.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::b41395b33e4b3d94efa98c28af4acd7d https://doi.org/10.1039/d2cy00155a Zobrazit plný text záznamu