The effect of heterogeneous acid–base catalysis on conversion of 5-hydroxymethylfurfural into a cyclopentanone derivative
| Autor: | Atsushi Satsuma, R. Kanao, Yutaka Ohira, Junya Ohyama |
|---|---|
| Rok vydání: | 2016 |
| Předmět: |
chemistry.chemical_classification
Base (chemistry) 010405 organic chemistry Chemistry 010402 general chemistry Cyclopentanone 01 natural sciences Pollution 0104 chemical sciences Catalysis Metal chemistry.chemical_compound Yield (chemistry) visual_art 5-hydroxymethylfurfural visual_art.visual_art_medium Environmental Chemistry Organic chemistry Derivative (chemistry) |
| Zdroj: | Green Chemistry. 18:676-680 |
| ISSN: | 1463-9270 1463-9262 |
| DOI: | 10.1039/c5gc01723h |
| Popis: | The effect of heterogeneous acid–base catalysis on conversion of 5-hydroxymethylfurfural (HMF) to 3-hydroxymethylcyclopentanone (HCPN) was investigated. It was demonstrated that acidic metal oxides, in particular Ta2O5, significantly enhanced the yield of HCPN due to their moderate Lewis acidity. |
| Databáze: | OpenAIRE |
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