Gas chromatographic determination of phosphorus, sulfur and halogens using a water-cooled torch with reduced-pressure helium microwave-induced plasma mass spectrometry

Autor:	W. Charles Story, Joseph A. Caruso
Rok vydání:	1993
Předmět:	Detection limit Bromine Chromatography Chlorotoluene Analytical chemistry chemistry.chemical_element Mass spectrometry Sulfur Analytical Chemistry chemistry Plasma torch polycyclic compounds Chlorine Gas chromatography Spectroscopy
Zdroj:	Journal of Analytical Atomic Spectrometry. 8:571
ISSN:	1364-5544 0267-9477
DOI:	10.1039/ja9930800571
Popis:	A system is described that utilizes a reduced-pressure water cooled microwave-induced plasma torch to interface a gas chromatograph with a plasma mass spectrometer. The detection limits vary with the compound used. For phosphorus in triethyl phosphate the detection limit is 86 pg and for chlorine in chlorotoluene, it is 22 pg. A seven component mixture was analysed simultaneously for compounds containing chlorine (m/z 35 and m/z 37), phosphorus (m/z 31), sulfur (m/z 32), bromine (m/z 79 and m/z 81) and iodine (m/z 127). A Supelco pesticide mixture was also analysed with simultaneous detection of chlorine and sulfur. Sub-nanogram detection limits were obtained for all elements studied.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::b406e5000ea891ef6330baa64bfbba52 https://doi.org/10.1039/ja9930800571 Zobrazit plný text záznamu