Etude de l'ion HC2O4− en solution aqueuse par spectrométrie infrarouge et Raman

Autor:	F. Bertin, M. Jaber, M. T. Forel
Rok vydání:	1979
Předmět:	Quantitative Biology::Biomolecules Aqueous solution Infrared Organic Chemistry Analytical chemistry General Chemistry Catalysis Ion chemistry.chemical_compound symbols.namesake Monomer chemistry symbols Physics::Chemical Physics Raman spectroscopy
Zdroj:	Canadian Journal of Chemistry. 57:876-882
ISSN:	1480-3291 0008-4042
DOI:	10.1139/v79-144
Popis:	The authors have investigated aqueous solution of the hydrogenooxalate ion by infrared and Raman spectroscopy. They show the existence of an equilibrium between a planar monomer structure linked by hydrogen bond to solvent molecules and an associated form. Such an equilibrium can provide a satisfactory explanation for the experimental spectra and their dependence upon temperature and concentration. The assignments for the monomeric form are supported by a normal coordinate analysis and by a calculation of the valence force field.
Databáze:	OpenAIRE
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