Characteristics and properties of hydoxyapatite derived by sol–gel and wet chemical precipitation methods

Autor: A. N. Natasha, Wan Dung Teng, A. Niakan, Hari Chandran, Judha Purbolaksono, Chou Yong Tan, L. T. Bang, C. Y. Ching, Singh Ramesh
Rok vydání: 2015
Předmět:
Zdroj: Ceramics International. 41:10434-10441
ISSN: 0272-8842
Popis: The synthesis of crystalline hydroxyapatite (HA) nanoparticles with expected microstructure is of primary importance because the process directly relates to the phase purity, morphology, and particle size of thefinal HA particles. In this work, different morphologies of HA powders were prepared via wet precipitation (HA‐Wp) and sol‐gel synthesis (HA‐Sg) methods. The results showed that pure HA powders were successfully obtained via the two different methods, in which HA‐Wp presented smaller crystallite size in accordance with the larger specific area compared with HA‐Sg powders. A high surface area of 97.4 m 2 g !1 was obtained in HA-Wp powder, whereas that of HA‐Sg powder was 9.0 m 2 g !1 . Upon calcinations at 800‐10001C, the calcined powders were found to be Ca-deficient apatites as HA-Wp and HA‐Sg powders decomposed to the secondary phase of!-TCP at 9001C and 10001C, respectively. Microstructural analysis showed significant difference in terms of HA morphologies produced via the two methods. The HA-Wp powder consisted of nanoscale needle-like structures with soft agglomerated particles, whereas HA‐Sg powder exhibited nanoglobular-like structures with hard agglomerated particles. The characteristics of nanocrystalline HA powder obtained from wet chemical precipitation is known to exhibit high surface activity as a bone substitute material. &2015 Elsevier Ltd and Techna Group S.r.l. All rights reserved.
Databáze: OpenAIRE
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