ChemInform Abstract: A Polymer-Supported Rhodium Catalyst that Functions in Polar Protic Solvents

Autor:	Rebecca A. Taylor, Michel R. Gagné, Brian P. Santora
Rok vydání:	2000
Předmět:	chemistry.chemical_classification Alkene chemistry.chemical_element General Medicine Polymer Photochemistry Catalysis Rhodium Matrix (chemical analysis) Hydroboration chemistry Polymer chemistry Polar Polymer supported
Zdroj:	ChemInform. 31
ISSN:	1522-2667 0931-7597
DOI:	10.1002/chin.200040019
Popis:	Highly cross-linked macroporous polymers are excellent supports for heterogenizing rhodium alkene hydrogenation and hydroboration catalysts. The permanent pore structure of the support enables high conversions and excellent yields with minimal workup (filtering). These heterogenized catalysts can be reused, and due to the permanent pore structure, they function in a broad range of solvents including polar protic. Control experiments reveal that catalysis occurs exclusively within the polymer matrix, and not due to leached catalyst.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::b3d5f89b14b60f8c407d41d8595dd8b0 https://doi.org/10.1002/chin.200040019 Zobrazit plný text záznamu Plný text