Free radicals in electrochemical reduction of 1-(nitrophenyl)-3,5-dicarbethoxy-4-phenyl-1,4-dihydropyridines

Autor:	R. Gavars, Gunars Duburs, Ya. P. Stradyn, B. S. Chekavichus, Larisa Baumane
Rok vydání:	1992
Předmět:	Chemistry Radical Organic Chemistry Dihydropyridine medicine Molecule Protonation Electrochemistry Photochemistry Medicinal chemistry medicine.drug
Zdroj:	Chemistry of Heterocyclic Compounds. 28:1280-1285
ISSN:	1573-8353 0009-3122
Popis:	In the primary electrochemical reduction of 1-(nitrophenyl)-3,5-dicarbethoxy-4-phenyl-1,4-dihydropyridine in DMF, free radicals of nitrophenyl type are formed; these are the products of a one-electron reduction of cathode-protonated molecules of the original compound. In alkaline DMF, where cathodic protonation of the initial compound is retarded, union-radicals of the starting material are generated in addition, together with p-nitrophenol free radicals.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::b3ae76618deefdfa93a78624aac42420 https://doi.org/10.1007/bf00532078 Zobrazit plný text záznamu Full text from SpringerLink