The chemistry of cobalt acetate: The isolation and crystal structure of the symmetric trimer,hexakis(μ-acetato)-μ3-oxo-tris(pyridine)tricobalt(III) perchlorate water solvate, [Co3O(CH3CO2)6(C5H5N)3][CiO4]·H2O

Autor:	Peter Turner, Trevor W. Hambley, John A. Klepetko, James K. Beattie, Anthony F. Masters
Rok vydání:	1996
Předmět:	Tris chemistry.chemical_element Trimer Crystal structure Oxygen Inorganic Chemistry Perchlorate chemistry.chemical_compound Crystallography Cobalt acetate chemistry Pyridine Materials Chemistry Physical and Theoretical Chemistry Cobalt
Zdroj:	Polyhedron. 15:2141-2150
ISSN:	0277-5387
DOI:	10.1016/0277-5387(95)00489-0
Popis:	The isolation and characterization by single-crystal X-ray diffraction (refined toR = 0.066, Rw = 0.058) of the perchlorate salt of the symmetric trimeric cation, [Co3O(CH3 CO2)6(C5H5N)3]+, are reported. The compound crystallizes in space groupP21/n (No. 14) as its water solvate, [Co3O(CH3CO2)6(C5H5N)3][CiO4]·H2O. The oxo-centred trimeric cations have a planar Co3ON3 core, with an equilateral triangle of cobalt atoms around the central oxygen and average distances 3.194(1) (Co3.Co) and 1.845(8)A˚(Co μ3-O).
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::b3a0e7d112f579a425108aad56a82882 https://doi.org/10.1016/0277-5387(95)00489-0 Zobrazit plný text záznamu Full Text from ScienceDirect