Catalytic activity of the palladium-hydrogen system in copper sulfate solutions

Autor:	Boris F. Lyakhov, L. N. Solodkova, A. Yu. Tsivadze, V. V. Chernyshov, S. V. Vashchenko, T. P. Puryaeva, I. I. Bardyshev
Rok vydání:	2014
Předmět:	Hydrogen Chemistry General Chemical Engineering Inorganic chemistry chemistry.chemical_element Copper sulfate General Chemistry engineering.material Copper Catalysis Coating engineering Hydrogen system Deposition (chemistry) Palladium
Zdroj:	Theoretical Foundations of Chemical Engineering. 48:793-798
ISSN:	1608-3431 0040-5795
Popis:	The currentless deposition of Cu2+, Ag+, and other cations from solutions of their salts takes place on the surface of hydrogen-saturated palladium (Pd-H). It is hypothesized that this process occurs via a catalytic chemical mechanism. It is demonstrated that 80–90% of the copper deposits onto Pd-H from a CuSO4 solution in the first hour of their contact. The Pd-H system with a thin palladium coating can finely purify solutions from Cu2+ when the amount of hydrogen in Pd exceeds the amount of Cu2+ in the solution.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::b379e73d31426b8bcccd66c2e9ac4674 https://doi.org/10.1134/s0040579514060062 Zobrazit plný text záznamu Plný text ve formátu PDF