Catalysis of Selective Hydrogen/Deuterium Exchange at Allylic Positions Using Deuterium Oxide

Autor:	Gulin Erdogan, Douglas B. Grotjahn
Rok vydání:	2010
Předmět:	chemistry.chemical_classification Allylic rearrangement Chemistry Alkene Oxide General Chemistry Hydrogen atom Photochemistry Catalysis chemistry.chemical_compound Deuterium Hydrogen–deuterium exchange Isomerization
Zdroj:	Topics in Catalysis. 53:1055-1058
ISSN:	1572-9028 1022-5528
DOI:	10.1007/s11244-010-9531-7
Popis:	Deuterated organic compounds can be prepared efficiently and cost effectively by the direct exchange of a hydrogen atom by a deuterium atom on a carbon center rather than classical synthetic procedures. H/D exchange is achieved at allylic positions of alkenes catalyzed by alkene isomerization catalyst 1. An outstanding degree of deuteration is achieved at positions accessible by isomerization in homogeneous and biphasic reaction settings.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::b37434496281436a69e3b9096abef809 https://doi.org/10.1007/s11244-010-9531-7 Zobrazit plný text záznamu Plný text ve formátu PDF