Carbon Nanoparticle/Hydrogenated Amorphous Carbon Composite Thin Films Formed in ECR Plasma

Autor: Aleksander Drenik, Maria Calafat, Richard Clergereaux, Pavel Yuryev, Aref Slim
Rok vydání: 2011
Předmět:
Zdroj: Plasma Processes and Polymers. 8:401-408
ISSN: 1612-8850
DOI: 10.1002/ppap.201000151
Popis: Composite thin films are deposited from acetylene in a microwave multipolar plasma excited at distributed electron cyclotron resonance in one single process. The composite consists of carbon-based nanoparticles embedded in a hydrogenated amorphous matrix. Effects of plasma duration and microwave power on the composite thin film are described along with the powder growth mechanisms. Indeed, two types of nanoparticles are formed: pure graphite-like and graphite-like shell with a metallic core. The first type grows from recombinations in the plasma phase, while core-shelled starts from a metallic core generated from the reactor walls. These metallic clusters can be heated while immersed in the plasma which leads to catalytic growth of powders.
Databáze: OpenAIRE