Room temperature synthesis of Cu nanocages through Ni-induced electroless process

Autor:	Yan Zhao, Yan Lu, Zhaohong Su, Jingnan Guo, Jingzhe Zhao, Xinli Hao, Dechong Ma
Rok vydání:	2013
Předmět:	Materials science Inorganic chemistry Hydrazine Amperometry Catalysis Metal chemistry.chemical_compound Colloid and Surface Chemistry Nanocages Octahedron chemistry visual_art Differential thermal analysis Scientific method visual_art.visual_art_medium
Zdroj:	Colloids and Surfaces A: Physicochemical and Engineering Aspects. 431:60-65
ISSN:	0927-7757
DOI:	10.1016/j.colsurfa.2013.04.019
Popis:	Designed octahedral Cu nanocages were successfully prepared at room temperature by introducing Ni induced electroless strategy. This strategy balanced the inhibitory effect of sodium oleate (SOA) in the room temperature reduction process. Reduction rate was markedly improved as Ni2+ increasing. The Ni-induced electroless Cu deposition mechanism was studied. The first deposited metallic Ni particles catalyzed the oxidation of hydrazine (N2H4·H2O) to give electrons. Cu2O intermediates captured the electrons and were reduced to Cu nanocages with SOA existence. Thermo-gravimetric and differential thermal analysis (TG–DTA) results illuminated that the Ni-induced Cu nanocages had higher oxidation resistance property in air atmosphere compared to Cu nanocages prepared without Ni inclusion. A well-defined, stable and fast amperometric response of glucose was observed when the Ni-induced Cu nanocages were constructed as non-enzymatic glucose sensor.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::b36a216b7de1d8f397c151d4fdf6ac89 https://doi.org/10.1016/j.colsurfa.2013.04.019 Zobrazit plný text záznamu Full Text from ScienceDirect