New Avenue for Limiting Degradation in NanoLi4Ti5O12 for Ultrafast-Charge Lithium-Ion Batteries: Hybrid Polymer–Inorganic Particles
| Autor: | Dharminder Laul, Karim Zaghib, Jean-Christophe Daigle, René Vieillette, Michel L. Trudeau, Yuichiro Asakawa, Mélanie Beaupré |
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| Rok vydání: | 2017 |
| Předmět: |
chemistry.chemical_classification
Battery (electricity) Materials science Mechanical Engineering Nanoparticle chemistry.chemical_element Bioengineering Nanotechnology 02 engineering and technology General Chemistry Polymer Electrolyte 010402 general chemistry 021001 nanoscience & nanotechnology Condensed Matter Physics 01 natural sciences Lithium-ion battery 0104 chemical sciences Titanium oxide chemistry General Materials Science Lithium 0210 nano-technology Hybrid material |
| Zdroj: | Nano Letters. 17:7372-7379 |
| ISSN: | 1530-6992 1530-6984 |
| DOI: | 10.1021/acs.nanolett.7b03119 |
| Popis: | Lithium titanium oxide (Li4Ti5O12)-based cells are a very promising battery technology for ultrafast-charge–discharge and long-cycle-life batteries. However, the surface reactivity of lithium titanium oxide in the presence of organic electrolytes continues to be a problem that may cause expansion of pouch cells. In this study, we report on the development of a simple and economical grafting method for forming hybrid polymer–Li4Ti15O12 nanoparticles, which can be successfully applied in lithium-ion batteries. This method utilizes a low-cost and scalable hydrophobic polymer that is applicable in industrial processes. The hybrid materials demonstrated exceptional capability for preventing the degradation of cells in accelerated aging and operating over 150 cycles at 1C and 45 °C. |
| Databáze: | OpenAIRE |
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