Existence of spin symmetry species in reorienting methyl groups at high temperatures
Autor: | S. Emid |
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Rok vydání: | 1981 |
Předmět: | |
Zdroj: | Chemical Physics Letters. 80:393-397 |
ISSN: | 0009-2614 |
DOI: | 10.1016/0009-2614(81)80135-2 |
Popis: | Reonentations of methyl groups in solids are symmetry restricted. Consequently long-lived spin symmetry species and reorientations coexist even at high temperatures. This is a refinement of the usual reorientation model. The possibility of creating an angular momentum imbalance between symmetry species is shown. The possibility of observing exponential relaxation is discussed. |
Databáze: | OpenAIRE |
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