Synthesis of Homochiral Co III – and Mn IV –[2.2]Paracyclophane Schiff Base Complexes with Predetermined Chirality at the Metal Centre
| Autor: | Paul S. Donnelly, Mark A. Rizzacasa, Jonathan M. White, Andrea J. North, Darran A. Loits, Stefan Bräse |
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| Rok vydání: | 2016 |
| Předmět: |
Schiff base
010405 organic chemistry Ligand Stereochemistry Enantioselective synthesis chemistry.chemical_element Manganese Planar chirality 010402 general chemistry 01 natural sciences 0104 chemical sciences Inorganic Chemistry Metal chemistry.chemical_compound Crystallography chemistry visual_art visual_art.visual_art_medium Chirality (chemistry) Cobalt |
| Zdroj: | European Journal of Inorganic Chemistry. 2016:3541-3544 |
| ISSN: | 1099-0682 1434-1948 |
| DOI: | 10.1002/ejic.201600750 |
| Popis: | The planar chiral Schiff base ligand 2, derived from (Rp)-5-formyl-4-hydroxy-[2.2]paracyclophane (FHPC) (1), was utilised to form a Λ-CoIII cis-β-octahedral metal complex 3 with complete control of the metal-centred chirality. In addition, a di-µ-oxo Λ,Λ-MnIV complex 4 was synthesised with control of both metal-centred and (P)-helical chirality. |
| Databáze: | OpenAIRE |
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