Autor: |
Qing-Hong Zhang, Ying-Xue Wang, Jing-Yu Guo, Ting Guan, Ji-Yu Tao, Teck-Peng Loh, Kai Zhao, Yu Zhang, Kun Ni |
Rok vydání: |
2021 |
Předmět: |
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Zdroj: |
Organic Chemistry Frontiers. 8:4086-4094 |
ISSN: |
2052-4129 |
DOI: |
10.1039/d1qo00605c |
Popis: |
A photoinitiated perfluoroalkylative coupling of enamides with perfluoroalkyl iodides and a visible-light-induced difluoroacetylation of enamides with ethyl bromodifluoroacetate have been developed, respectively. These transformations allow the efficacious and straightforward incorporation of biologically and physiologically privileged fluoro-containing moieties into synthetically eminent enamide scaffolds with excellent regio- and stereoselectivities under mild and environmentally friendly conditions. |
Databáze: |
OpenAIRE |
Externí odkaz: |
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