Metal-free catalytic C-H bond activation and borylation of heteroarenes

Autor:	Marc-André Légaré, Étienne Rochette, Frédéric-Georges Fontaine, Marc-André Courtemanche
Rok vydání:	2015
Předmět:	Multidisciplinary Chemistry Boranes Borane Borylation Catalysis Metal chemistry.chemical_compound Transition metal Metal free visual_art visual_art.visual_art_medium Organic chemistry Surface modification
Zdroj:	Science. 349:513-516
ISSN:	1095-9203 0036-8075
DOI:	10.1126/science.aab3591
Popis:	A metal-free catalyst born of frustration Boron (a Lewis acid) and nitrogen or phosphorus fragments (both Lewis bases) tend to pair up. Keeping them separated on opposite ends of the same molecule creates a “frustrated” Lewis pair. Such molecules can manifest powerful reactivity, such as scission of the hydrogen-hydrogen bond in H 2 . Légaré et al. now extend this reactivity to the cleavage of carbon-hydrogen bonds in heteroaromatic compounds such as furans and pyrroles (see the Perspective by Bose and Marder). Their frustrated Lewis pair complex catalyzed borylation of these compounds. The selectivity pattern of the reaction complemented that seen with the metal catalysts conventionally used. Science , this issue p. 513 ; see also p. 473
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::b3164f4393f03da5e5c67722d9bf35cb https://doi.org/10.1126/science.aab3591 Zobrazit plný text záznamu Plný text ve formátu PDF