Extraction of MAu(CN)2Ion Pairs into Organic Solvents from Aqueous Solution

Autor:	M. D. Adams
Rok vydání:	1999
Předmět:	Solvent Aqueous solution Chemistry Process Chemistry and Technology General Chemical Engineering Inorganic chemistry Extraction (chemistry) Filtration and Separation General Chemistry Dielectric Ion pairs Solubility
Zdroj:	Separation Science and Technology. 34:2039-2060
ISSN:	1520-5754 0149-6395
Popis:	Factors influencing the extraction and association of MAu(CN)2 ion pairs in organic solvents are elucidated. For extraction of aurocyanide ion pairs with small cations (H+, Li+, Na+, K+), the most important factor is the solubility of water in the solvent. High extraction efficiencies are related to low association constants for these cations. For extraction of aurocyanide ion pairs with larger, less hydrated cations (Cs+, NEt+ 4), other solvent-specific parameters, such as dielectric constant and hydrogen-bonding ability, play a role.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::b30e44f27ee9a44c75a6fbb4a3cd4b99 https://doi.org/10.1081/ss-100100754 Zobrazit plný text záznamu