Synthesis and characterization of multiply substituted lacunar macrobicyclic complexes of nickel(II), a representative crystal structure, and preparation of corresponding free ligands
| Autor: | Bohdan Korybut-Daszkiewicz, Norman Herron, James H. Cameron, Alan J. Jircitano, M. Y. Chavan, Nathaniel W. Alcock, Daryle H. Busch, Masaaki Kojima, B. K. Coltrain, Gary L. Neer |
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| Rok vydání: | 1984 |
| Předmět: |
chemistry.chemical_classification
Chemistry chemistry.chemical_element Crystal structure Nuclear magnetic resonance spectroscopy Characterization (materials science) Inorganic Chemistry Crystallography Nickel X-ray crystallography Chemical solution Molecule Physical and Theoretical Chemistry Inorganic compound |
| Zdroj: | Inorganic Chemistry. 23:903-914 |
| ISSN: | 1520-510X 0020-1669 |
| DOI: | 10.1021/ic00175a022 |
| Popis: | Etude de la structure cristalline de l'hexafluorophosphate de (dibenzyl-3,11 dimethyl-14,20 diphenyl-2,12 hexaaza-3,11,15,19,22,26 tricyclo [11.7.7.1 5,9 ] octacosanonaene-1,5,7,9(28),12,14,29,21,16) nickel (II). Cristallisation dans le systeme monoclinique, groupe P2 1 /c et affinement jusqu'a R=8,3%. La structure illustre les contraintes steriques pesant sur le site lacunaire et la forme des substituants peripheriques. Proprietes electroniques et spectroscopiques d'une selection de complexes de nickel avec differents substituants |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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