Preparation and characterization of a volatile uranyl compound, bis(1,1,1,5,5,5-hexafluoro-2,4-pentanedionato)dioxouranium-tetrahydrofuran

Autor:	R. B. Hall, Allan J. Jacobson, Martin B. Dines, A. Kaldor, J.C. Scanlon, G. M. Kramer
Rok vydání:	1980
Předmět:	Chemistry Vapor pressure Inorganic chemistry Infrared spectroscopy Crystal structure Uranyl Inorganic Chemistry Crystallography chemistry.chemical_compound Mass spectrum Molecule Physical and Theoretical Chemistry Tetrahydrofuran Monoclinic crystal system
Zdroj:	Inorganic Chemistry. 19:1340-1347
ISSN:	1520-510X 0020-1669
DOI:	10.1021/ic50207a048
Popis:	A volatile uranyl compound UO/sub 2/((CF/sub 3/CO)/sub 2/CH)/sub 2/.THF with a vapor pressure of 0.7 torr at 100/sup 0/C has been prepared. The compound has high thermal stability and is suitable for studies of laser-induced isotope separation. The compound has been characterized by its IR, UV, NMR, fluorescence, and mass spectra and other physical and chemical properties including an X-ray structural determination. The molecule contains a linear uranyl ion equatorially surrounded by a pentagon of oxygen atoms. The chelating anions are tilted slightly in a boatlike configuration from this plane. The crystals are monoclinic,P2/sub 1/c, with a = 8.540 (3) A, b = 9.110 (4) A, c = 28.884 (11) A, ..beta.. = 94.26 (3)/sup 0/, and Z = 4.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::b2f2b3948f0e237ebadbfa3974a60574 https://doi.org/10.1021/ic50207a048 Zobrazit plný text záznamu