Autor: | Leonid I. Belen’kii, Mikhail M. Krayushkin, S. I. Luiksaar, I. S. Poddubnyi |
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Rok vydání: | 2000 |
Předmět: | |
Zdroj: | Chemistry of Heterocyclic Compounds. 36:1172-1176 |
ISSN: | 0009-3122 |
DOI: | 10.1023/a:1002816615941 |
Popis: | The reaction of N-(4-pyridyl)pyridinium and 4-chloropyridinium salts obtained from 1-trichloromethyl-2,4,6-trimethylbenzene and pyridine with N-nucleophiles such as piperidine and morpholine and with C-nucleophiles such as N,N-dimethylaniline and indole proceeds through hetarylation and gives the corresponding 4-substituted pyridines. N-(α,α-Dichlorobenzyl)pyridinium and N,N'-(α-chlorobenzylidene)bispyridinium salts obtained from trichloromethylbenzene do not undergo hetarylation. |
Databáze: | OpenAIRE |
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