Transition metal catalysis in organic synthesis: reflections, chirality and new vistas

Autor:	Štěpán Vyskočil, Pavel Kočovský, Andrei V. Malkov, Guy C. Lloyd-Jones
Rok vydání:	1999
Předmět:	Allylic rearrangement Stereochemistry Chemistry General Chemical Engineering Enantioselective synthesis General Chemistry Oxidative addition chemistry.chemical_compound Suzuki reaction Heck reaction Polymer chemistry Organic synthesis Chirality (chemistry) Amination
Zdroj:	Pure and Applied Chemistry. 71:1425-1433
ISSN:	1365-3075 0033-4545
DOI:	10.1351/pac199971081425
Popis:	The power of transition metal catalysis as a tool in organic synthesis is exemplified by the recent progress in the following areas: (i) diastereocontrol of Pd(0)-, Mo(0)-, and Ni(0)- catalyzed allylic substitution; (ii) Pd(0)-catalyzed asymmetric allylic substitution; (iii) Hartwig-Buchwald amination; and (iv) Suzuki coupling. Development of novel, bidentate binaphthyl ligands (MAP) and their unique mode of P,Cs-coordination is also described.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::b2cc5b4b7dda35fe5367b65dcdf7058d https://doi.org/10.1351/pac199971081425 Zobrazit plný text záznamu