Asymmetric synthesis of α-chiral dihydrocinnamates by catalytic reductive aldol coupling and subsequent dehydroxylation

Autor:	Takushi Shiomi, Toru Hashimoto, Jun-ichi Ito, Hisao Nishiyama
Rok vydání:	2007
Předmět:	Organic Chemistry Enantioselective synthesis chemistry.chemical_element Biochemistry Coupling reaction Rhodium Catalysis Benzaldehyde chemistry.chemical_compound chemistry Aldol reaction Asymmetric carbon Drug Discovery Polymer chemistry Cinnamates Organic chemistry
Zdroj:	Tetrahedron. 63:12883-12887
ISSN:	0040-4020
DOI:	10.1016/j.tet.2007.10.055
Popis:	Optically active dihydrocinnamate derivatives bearing the chiral carbon center at α-position were synthesized by Rh(Phebox)-catalyzed asymmetric reductive aldol coupling reaction with substituted cinnamates and benzaldehyde derivatives and subsequent dehydroxylation reaction.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::b2c9d38c1cfe2eb1f0fde380b6844a0d https://doi.org/10.1016/j.tet.2007.10.055 Zobrazit plný text záznamu Full Text from ScienceDirect