(Isothiocyanato)[(1RS,4RS,8SR,11SR)-1,4,8,11-tetraazacyclotetradecane]copper(II) Thiocyanate, [Cu(NCS)(cyclam)](SCN)
| Autor: | Yuh Liang Liu, Yaw Shiun Hong, Chung Sun Chung, Tian Huey Lu, Chiung Chia Huang, T. H. Tahirov |
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| Rok vydání: | 1996 |
| Předmět: |
chemistry.chemical_classification
Quantitative Biology::Neurons and Cognition Thiocyanate Chemistry Ligand Inorganic chemistry General Medicine Crystal structure General Biochemistry Genetics and Molecular Biology Metal Crystallography chemistry.chemical_compound visual_art Cyclam visual_art.visual_art_medium Molecule Condensed Matter::Strongly Correlated Electrons Counterion Coordination geometry |
| Zdroj: | Acta Crystallographica Section C Crystal Structure Communications. 52:1093-1095 |
| ISSN: | 0108-2701 |
| DOI: | 10.1107/s0108270195016519 |
| Popis: | The crystal structure of the title compound, [Cu(NCS)(C 10 H 24 N 4 )](SCN), has been determined by X-ray diffraction. A mirror plane passes through the metal atom and bisects the complex with the isothiocyanato ligand lying on the plane. The Cu II ion is five-coordinate in a distorted square-pyramidal environment, with four amine N atoms in equatorial positions and the isothiocyanate N atom in an axial position ; its coordination geometry is normal, with the equatorial Cu-N distances shorter than the axial one. The unbound SCN - counterion is statistically disordered. |
| Databáze: | OpenAIRE |
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