Thermo- and photoinduced properties of the Fe(III) complexes with the pentadentate ligand according to the EPR data
Autor: | A. A. Sukhanov, L. V. Mingalieva, Igor V. Ovchinnikov, O. A. Turanova, G. I. Ivanova, T. A. Ivanova |
---|---|
Rok vydání: | 2013 |
Předmět: | |
Zdroj: | Russian Journal of Coordination Chemistry. 39:598-602 |
ISSN: | 1608-3318 1070-3284 |
DOI: | 10.1134/s107032841308006x |
Popis: | Compounds [Fe(Salten)L]BPh4 (Salten = N,N-bis[(2-oxyphenyl)methylene]-4-azaheptane-1,7-diamine; L = Him (I) and Pic (II)) were studied by the EPR method in the temperature range from 5 to 300 K. The thermoinduced spin transition is observed in compound II. Its thermodynamic parameters and parameters of the ground electronic low-spin state were determined. The effect of decreasing the intensity of the stationary EPR signal upon laser pulse irradiation at λ = 532 nm was observed in the studied samples. |
Databáze: | OpenAIRE |
Externí odkaz: |