Production of the NaHg Molecule by Reactive Three-Body Collisions following Energy-Transferring Processes of Laser-Excited Na(3 2P) Atoms

Autor:	Kurt Friedrich Iskra, Stoyan Dinev, Ursula Domiaty, Dieter Gruber, Laurentius Windholz
Rok vydání:	1996
Předmět:	Chemistry Sodium General Engineering chemistry.chemical_element Laser law.invention law Excited state Laser intensity Molecule Physical and Theoretical Chemistry Atomic physics Particle density Excitation Chemiluminescence
Zdroj:	The Journal of Physical Chemistry. 100:7078-7084
ISSN:	1541-5740 0022-3654
DOI:	10.1021/jp9531671
Popis:	We report on the production of the NaHg molecule via resonant excitation of the sodium D-lines following energy-pooling collisions of laser-excited Na(3 2P) atoms. In addition to the chemiluminescence on the red NaHg(II1/2−X1/2) band system, we observed emission on the blue-band system. Production mechanisms as well as the dependence on particle density and excitation laser intensity are discussed, and the rate coefficients are determined.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::b27aa79f88972d4f2e1d3a4053e4978f https://doi.org/10.1021/jp9531671 Zobrazit plný text záznamu