N-tert-Butanesulfinyl Imines in Alkaloid Synthesis: Stereoselective Synthesis of (R)-Coniine and Formal Synthesis of (S)-δ-Coniceine¹

Autor:	Biswanath Das, Kongara Damodar, Maram Lingaiah, Nisith Bhunia
Rok vydání:	2011
Předmět:	Formal synthesis chemistry.chemical_compound Chemistry Stereochemistry Organic Chemistry Stereoselectivity Indolizidine Catalysis
Zdroj:	Synthesis. 2011:2478-2482
ISSN:	1437-210X 0039-7881
DOI:	10.1055/s-0030-1260117
Popis:	A stereoselective synthesis of the hemlock alkaloid ( R)-coniine and a formal synthesis ofthe indolizidine alkaloid ( S)-δ-coniceinewere achieved by means of a highly diastereoselective Barbier-typeindium-mediated allylation strategy involving ( S)-( N- TERT-butanesulfinyl)imines.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::b254b473066bfc4cebf3a44b2f9908ea https://doi.org/10.1055/s-0030-1260117 Zobrazit plný text záznamu