The syntheses and electrochemistry of some molybdenum mononitrosyl complexes containing the tripodal ligand [Co(η5-C5H5){P(O)(OEt)2}3]–

Autor:	Jon A. McCleverty, Sithy S. Salam, Chris Jones
Rok vydání:	1988
Předmět:	Stereochemistry chemistry.chemical_element General Chemistry Nuclear magnetic resonance spectroscopy Electrochemistry Medicinal chemistry chemistry.chemical_compound Monomer chemistry Molybdenum Tripodal ligand Moiety Phenols Bimetallic strip
Zdroj:	J. Chem. Soc., Dalton Trans.. :2769-2773
ISSN:	1364-5447 0300-9246
DOI:	10.1039/dt9880002769
Popis:	The bimetallic complex [Mo(NO)(CO)2L](L =[Co(η5-C5H5){P(O)(OEt)2}3]–) may be oxidatively halogenated using iodine to give [Mo(NO)Ll2] which is a monomeric complex containing a 16-electron {Mo(NO)}4 moiety. This di-iodide reacts with p-toluidine to give [Mo(NO)Ll(NHC6H4Me-p)] but is decomposed by alcohols or phenols. Reactions with the chelating ligands toluene-3,4-dithiol and 2-aminobenzenethiol afford [Mo(NO)L{SC6H3(Me)S}] and [Mo(NO)L(SC6H4NH)] respectively.
Databáze:	OpenAIRE
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