Crystal structure of anhydrous nitrates and their complexes. Part VII. 1.5 Dinitrogen tetroxide solvate of iron(III) nitrate

Autor:	Leslie J. Blackwell, Stephen C. Wallwork, Ernest K. Nunn
Rok vydání:	1975
Předmět:	chemistry.chemical_classification Denticity Dinitrogen tetroxide Inorganic chemistry Salt (chemistry) General Chemistry Crystal structure Ion Dodecahedron chemistry.chemical_compound Crystallography chemistry Anhydrous Iron(III) nitrate
Zdroj:	Journal of the Chemical Society, Dalton Transactions. :2068
ISSN:	1364-5447 0300-9246
DOI:	10.1039/dt9750002068
Popis:	Crystal structure determination has shown that this solvate exists in the form [NO]+3[NO3]–[Fe(NO3)4]–2 in which there is close association between the three [NO]+ and the [NO3]– ions to form a grouping [N4O6]2+. The nitrogen atom of each [NO]+ lies approximately along the bisector of each O–N–O angle of the nitrate ion with ON+⋯ O2NO2 distances ranging from ca. 2.4 to 2.8 A and the NO+ axes tilted at angles ranging 10–51° out of the plane of the nitrate ion. The two crystallographically independent tetranitratoferrate(III) ions have the same trigonal dodecahedral structure as found in the tetraphenylarsonium salt with symmetrically bidentate nitrato-groups.
Databáze:	OpenAIRE
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