Synthesis and hydrophosphorylation of π-complexes of dibenzylideneacetone and cyclic conjugated dienones with homocarbonyl and carbonylcyclopentadienyl molybdenum compounds
| Autor: | Arcady I. Kuramshin, S. Z. Vatsadze, R. A. Cherkasov, Vladimir I. Galkin |
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| Rok vydání: | 2016 |
| Předmět: |
Diketone
Denticity 010405 organic chemistry Chemistry Ligand chemistry.chemical_element General Chemistry Conjugated system 010402 general chemistry 01 natural sciences Medicinal chemistry 0104 chemical sciences chemistry.chemical_compound Cyclopentadienyl complex Dibenzylideneacetone Molybdenum Organic chemistry Reactivity (chemistry) |
| Zdroj: | Russian Journal of General Chemistry. 86:645-655 |
| ISSN: | 1608-3350 1070-3632 |
| DOI: | 10.1134/s1070363216030221 |
| Popis: | Reactions of dibenzylideneacetone and cyclic cross-conjugated dienones with hexacarbonylmolybdenum(0) and bis[tricarbonyl(cyclopentadienyl)molybdenum(0)] afforded the corresponding complexes with η2-(C=C),η2-(C=O) coordination of the diketone to metal center, regardless of the ligand structure and initial molybdenum compound. The reactivity of the multidentate ligands may change as a result of coordination. |
| Databáze: | OpenAIRE |
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