Structural characterization of a four-electron donating, doubly-bridging isocyanide in (μ-p-CH3C6H4NC)Mn2(Ph2PCH2PPh2)2(CO)4

Autor:	Alan L. Balch, Linda S. Benner, Marilyn M. Olmstead
Rok vydání:	1978
Předmět:	Chemistry Ligand Stereochemistry Isocyanide Organic Chemistry Bent molecular geometry chemistry.chemical_element Manganese Electron Biochemistry Inorganic Chemistry Crystallography chemistry.chemical_compound Materials Chemistry Molecule Single bond Physical and Theoretical Chemistry
Zdroj:	Journal of Organometallic Chemistry. 159:289-298
ISSN:	0022-328X
DOI:	10.1016/s0022-328x(00)93806-3
Popis:	X-Ray crystallographic analysis of (μ-p-CH3C6H4NC)Mn2(Ph2PCH2PPh2)2(CO)4 is reported. The molecule consists of two manganese atoms joined by a single bond and bridged by two trans diphosphine ligands and the isocyanide. There are two terminal CO groups per Mn. The isocyanide carbon donates a pair of electrons to one Mn (MnC = 1.81 A) while the CN unit donates a second pair of electrons to the other Mn (MnN = 2.12 A, MnC = 2.14 A). The isocyanide is strongly bent with a CNC(phenyl) angle of 137°. The bonding of the isocyanide ligand is discussed.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::b2209126949401b2c6b153261fb78159 https://doi.org/10.1016/s0022-328x(00)93806-3 Zobrazit plný text záznamu