A porous luminescent Zn-MOF for selective probing Fe3+ and nitrophenolic compounds
| Autor: | Huijun Li, Xinglei He, Zhang Bo, Meijie Su, Yuan Wang, Zhou-Qing Xu |
|---|---|
| Rok vydání: | 2020 |
| Předmět: |
Quenching
Materials science Ligand 02 engineering and technology 010402 general chemistry 021001 nanoscience & nanotechnology 01 natural sciences 0104 chemical sciences Inorganic Chemistry chemistry.chemical_compound Crystallography chemistry Materials Chemistry Physical and Theoretical Chemistry Absorption (chemistry) 0210 nano-technology Luminescence Bifunctional Porosity Excitation |
| Zdroj: | Inorganic Chemistry Communications. 111:107644 |
| ISSN: | 1387-7003 |
| DOI: | 10.1016/j.inoche.2019.107644 |
| Popis: | A porous luminescent MOF {[Zn(L)]·4H2O·2CH3CN}n (HPU-12) based on a bifunctional ligand, 5-(3,5-Di-pyridin-4-yl- [1] , [2] , [4] triazol-1-ylmethyl)-isophthalic acid (H2L), has been synthesized. Structural analysis shows that the two-fold interpenetrated HPU-12 contains 3D pore channels covered with N- and O-coordinated active sites. The luminescence investigation demonstrates that the luminescent HPU-12 can realize the selective detection for Fe3+ by quenching the emission of the HPU-12 via the interaction between the Fe3+ and N and O atoms in the pore channels. In addition, the luminescence of the HPU-12 could be selectively and sensitively quenched by nitrophenolic compound because of the overlap of the absorption of the nitrophenolic compound with the excitation and emission of HPU-12. |
| Databáze: | OpenAIRE |
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