2p Photoelectron spectroscopy of the late 3d transition metal atoms
| Autor: | K. Godehusen, Michael Martins, T. Wolff, Tobias Richter, Peter Zimmermann |
|---|---|
| Rok vydání: | 2004 |
| Předmět: |
Radiation
Valence (chemistry) Metal K-edge Chemistry Configuration interaction Condensed Matter Physics Electron spectroscopy Atomic and Molecular Physics and Optics Metal L-edge Electronic Optical and Magnetic Materials X-ray photoelectron spectroscopy Physics::Atomic and Molecular Clusters Physics::Atomic Physics Physical and Theoretical Chemistry Atomic physics Valence electron Spectroscopy |
| Zdroj: | Journal of Electron Spectroscopy and Related Phenomena. :345-350 |
| ISSN: | 0368-2048 |
| Popis: | Employing electron spectrometry in conjunction with third generation synchrotron radiation (SR), we present a short overview of the 2p photoelectron spectroscopy of free 3d transition metal atoms. In particular, this paper will focus on the late transition metals from Cr to Cu and a comparison of the free atoms to several compound systems. The atomic experimental spectra are compared to theoretical spectra based on Hartree-Fock (HF) and configuration interaction (CI) calculations. In general a good agreement between experiment and theory is found already for single configuration HF calculations and the observed satellites in the atomic 2p photoelectron spectra (PES) can be attributed to a recoupled 3d valence shell. However, for Ni mixing of several configurations in the final state have to be taken into account. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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