Beyond the long-wavelength approximation in electromagnetic Rydberg–Rydberg couplings

Autor: M. Sobczak, R. Parzyński
Rok vydání: 2003
Předmět:
Zdroj: Optics Communications. 225:123-130
ISSN: 0030-4018
DOI: 10.1016/j.optcom.2003.08.008
Popis: We give a method, to a great extent analytical, for calculating the high-n intrashell (Δn=0) and intershell (Δn≠0) Rydberg–Rydberg matrix elements of the full electric operator of the multipolar Hamiltonian for the atom – electromagnetic radiation interaction. Our method is an alternative to the recent approach of Komninos, Mercouris and Nicolaides [Phys. Rev. A 65 (2002) 043412] being predominantly a numerical one. Wherever a comparison has been possible, the two approaches are shown to give the same results. Within our approach we give a number of examples which should discourage the use of the electric-dipole approximation, and generally the long-wavelength approximation, in some problems of high-n Rydberg state physics.
Databáze: OpenAIRE