Structures and fusion parameters of methoxycarbonyl-benzenes and -naphthalenes

Autor:	Shizu Fujishima, Yasuhiko Dozen, Haruo Shingu
Rok vydání:	1978
Předmět:	Fusion Crystallography Computational chemistry Chemistry Enthalpy Melting point Molecule Physical and Theoretical Chemistry Condensed Matter Physics Instrumentation
Zdroj:	Thermochimica Acta. 25:209-216
ISSN:	0040-6031
DOI:	10.1016/0040-6031(78)85008-4
Popis:	The heats of fusion of methoxycarbonyl-benzenes (12 isomers) and -naphthalenes (32 isomers) have been determined by the differential scanning calorimetric method and the correlation of numbers and positions of methoxycarbonyl groups against the parameters of fusion (melting point, enthalpy and entropy) are discussed. The enthalpy—entropy relationship shows two correlation lines depending on the symmetry of the molecules including the positions of the substituents.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::b1cba3f559efbd79320a1c7cbf01a52f https://doi.org/10.1016/0040-6031(78)85008-4 Zobrazit plný text záznamu