Electeochemically generated free radicals

Autor:	A. Sh. Mukhtarov, B. D. Chernokal'skii, Yu. G. Galyametdinov, A. V. Il'yasov, A. A. Vafina, A. S. Gel'fond, Yu. M. Kargin, B. V. Mel'nikov, I. D. Morozova
Rok vydání:	1972
Předmět:	inorganic chemicals Radical Inorganic chemistry Oxide chemistry.chemical_element General Chemistry Beta scission Electrochemistry Photochemistry Chemical reaction Delocalized electron chemistry.chemical_compound chemistry Molecular orbital Arsenic
Zdroj:	Bulletin of the Academy of Sciences of the USSR Division of Chemical Science. 21:2111-2114
ISSN:	1573-9171 0568-5230
DOI:	10.1007/bf00855277
Popis:	1. The mechanism of the polarographic reduction of nitrophenyldiethylarsines, their oxides and sulfides in aprotonic medium was studied. Schemes of the subsequent chemical reactions after the reception of a second electron by these systems were proposed. 2. New organoarsenic anion radicals were produced by electrochemical reduction and investigated by the ESR method. Their stability was estimated. The delocalization of the unshared electron in them was studied, and possible causes of the appreciable decrease in the spin density on the arsenic atom in the transition from anion radicals with a tetra-to a tricoordinated arsenic atom were considered.
Databáze:	OpenAIRE
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