Kinetics of the sulfodeacylation of 2,4,6,2?,6?-pentamethylbenzophenone, a process comprising successive first-order reactions occurring by two alternative routes

Autor:	Gerald F. Moxon, David N. Waters, Esmat F. Saad, Peter H. Gore
Rok vydání:	1982
Předmět:	chemistry.chemical_classification Ketone Chemistry Fission Organic Chemistry Kinetics Sulfuric acid Cleavage (embryo) First order Biochemistry Medicinal chemistry Inorganic Chemistry chemistry.chemical_compound Scientific method Carbon dioxide Organic chemistry Physical and Theoretical Chemistry
Zdroj:	International Journal of Chemical Kinetics. 14:55-62
ISSN:	1097-4601 0538-8066
DOI:	10.1002/kin.550140107
Popis:	Mesityl 2,6-xylyl ketone in 89.8% (w/w) sulfuric acid undergoes cleavage to give mesitylenesulfonic acid, xylenesulfonic acid, and carbon dioxide as final products. The reaction has been analyzed in terms of a series of first-order reactions. Of the two possible reaction paths available it was shown that fission at the mesityl group is responsible for about 98.5% of the overall initial reaction at 25°C.
Databáze:	OpenAIRE
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