Zweikernkomplexe mit heterometallischer Palladium-Platin-Bindung/Binuclear Complexes Containing a Heterometallic Palladium-Platinum Bond

Autor:	Alfred Kühn, Helmut Werner
Rok vydání:	1978
Předmět:	Metal NMR spectra database Crystallography chemistry Oxidation state Molar ratio visual_art visual_art.visual_art_medium chemistry.chemical_element General Chemistry Platinum Spectral line Palladium
Zdroj:	Zeitschrift für Naturforschung B. 33:1360-1364
ISSN:	1865-7117 0932-0776
DOI:	10.1515/znb-1978-1134
Popis:	The reaction of C5H5Pt(2-RC3H4) (R = H, CH3) with PdL2 (L = P(i-C3H7)3, P(c-C6H11)3) in the molar ratio of 1:1 produces the binuclear complexes (μ-C5H5)(μ-2-RC3H4)PdPtL2 in which the metal atoms have the formal oxidation state + 1. Based on the 1H, 13C and 31P NMR spectra it is assumed that the structures of the new complexes are analogous to those of the corresponding Pd2 and Pt2 compounds but that they contain a heterometallic palladium-to-platinum bond. The synthesis and the spectra of the bis(allyl) complex (μ-2-CH3C3H4)2PdPt[P(i-C3H7)3]2 are also reported.
Databáze:	OpenAIRE
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