Thermochemistry of Metal Nitrides in the Ca/Zn/N System

Autor:	J. M. McHale, Glen R. Kowach, Alexandra Navrotsky, Francis J. DiSalvo
Rok vydání:	1996
Předmět:	Chemistry Organic Chemistry Inorganic chemistry Oxide General Chemistry Calorimetry Nitride Acceptor Catalysis Metal Solvent chemistry.chemical_compound visual_art visual_art.visual_art_medium Thermochemistry Ternary operation
Zdroj:	Chemistry - A European Journal. 2:1514-1517
ISSN:	1521-3765 0947-6539
DOI:	10.1002/chem.19960021207
Popis:	The energetics of ternary oxide formation is reasonably well understood, but little is known of the energetics of ternary nitride formation. We have developed new procedures for high-temperature oxide melt solution calorimetry on metal nitrides and employed them to study compounds in the Ca/Zn/N system. The calorimetry utilized the easy reduction of MoO3 in the solvent to supply a pathway for rapid oxidation of “N3–” to N2 gas. These experiments represent the first high-temperature solution calorimetry of ternary metal nitrides. The results indicate that Ca3N2 acts as a basic nitride analogous to CaO in oxide systems, while Zn3N2 acts as an acidic nitride (“N3–” acceptor) in this ternary nitride system.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::b1881a4eafe295f77a5344657cc45c58 https://doi.org/10.1002/chem.19960021207 Zobrazit plný text záznamu Plný text