Synthesis of 1,2,4-Trioxepanes and 1,2,4-Trioxanes via H2O2-Mediated Reaction of Tertiary Carbinols

Autor:	Sanjeev K. Shukla, Niraj K. Naikade, Prem P. Yadav, Makthala Ravi, Ranjani Maurya, Parul Chauhan, Devireddy Anand
Rok vydání:	2012
Předmět:	chemistry.chemical_compound chemistry Benzilic acid Organic Chemistry Hydrogen peroxide Combinatorial chemistry
Zdroj:	Synlett. 24:173-176
ISSN:	1437-2096 0936-5214
DOI:	10.1055/s-0032-1317958
Popis:	A facile and efficient method for the synthesis of 1,2,4-trioxepanes and 1,2,4-trioxanes from different carbinols having cyclopropyl and phenyl substituents has been developed. The corresponding hydroxyhydroperoxides were synthesized from 30% H 2 O 2 mediated reaction of carbinols in acidic conditions. This method provided access to novel 6,6-diaryl-substituted 1,2,4-trioxanes derived from benzilic acid.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::b184525c491d1c5f4b21688833b2f07c https://doi.org/10.1055/s-0032-1317958 Zobrazit plný text záznamu