Unstable intermediates. Part CLXII. Electron spin resonance studies of ClOCl+, FClO+, and Cl4 +

Autor:	Raymond S. Eachus, Martyn C. R. Symons
Rok vydání:	1976
Předmět:	Principal direction Plane (geometry) Radical Antimony pentachloride chemistry.chemical_element General Chemistry Spectral line law.invention Crystallography chemistry.chemical_compound Planar chemistry Computational chemistry law Chlorine Electron paramagnetic resonance
Zdroj:	Journal of the Chemical Society, Dalton Transactions. :431
ISSN:	1364-5447 0300-9246
DOI:	10.1039/dt9760000431
Popis:	Fluid and solid-state e.s.r. spectra for the title radicals formed from molecular chlorine and antimony pentachloride are described and approximate orbital populations derived therefrom. The novel radical Cl4+, only detected at 77 K, is throught to be planar, being formed from Cl2+ and Cl2 by a weak π*–π* interaction. Structural considerations suggest the assignment: gx= 2.00 gy= 2.031, gz= 2.125 and Ax(35Cl)= 48G, Ay= O ± 4 G, and Az= 0 ± 4 G, where x is the principal direction of the combined π* orbital, z is the direction of the original σ bonds, and y is normal to the plane.
Databáze:	OpenAIRE
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