Trinuclear cationic silver nanoclusters based-on bis-(phosphine) ligands and stabilized by CF3SO3−anions
| Autor: | Chun-Hui Xue, Jiuyu Ji, Li Li, Bao-Kuan Chen, Kun Zhou, Yanfeng Bi, Chu-Xia Han, Zi-Mo Shao |
|---|---|
| Rok vydání: | 2021 |
| Předmět: |
Photocurrent
Thermogravimetric analysis 010405 organic chemistry Chemistry Cationic polymerization General Chemistry 010402 general chemistry Electrochemistry 01 natural sciences Catalysis 0104 chemical sciences Nanoclusters Crystallography chemistry.chemical_compound Materials Chemistry Luminescence Phosphine Powder diffraction |
| Zdroj: | New Journal of Chemistry. 45:7555-7563 |
| ISSN: | 1369-9261 1144-0546 |
| DOI: | 10.1039/d1nj00873k |
| Popis: | Three trinuclear silver nanoclusters, [Ag3(dppm)3(tBuCC)](CF3SO3)2 (1), [Ag3(dppm)3(CO3)(CH3OH)](CF3SO3)·H2O (2) and [Ag3(dppm)3(Cl)2](CF3SO3)·3DMF (3) (dppm = 1,2-bis-(diphenylphosphino)methane) were obtained and characterized by a series of techniques including single-crystal X-ray diffraction (SCXRD), Fourier transform infrared spectrometry (FT-IR), powder X-ray diffraction (PXRD) and thermogravimetric analysis (TGA). In the three compounds, their main body skeletons are made up of similar Ag3 cores shaped in a silver triangle. All the three compounds consist of three silver atoms, three dppm bis-(phosphine) ligands, which are further stabilized by CF3SO3− anions. While the other auxiliary ligands, tBuCC−, CO32− and Cl− are separately attached to similar Ag3 cores, making them structurally different. Moreover, the luminescence properties, photocurrent responses and electrochemical properties of compounds 1–3 have been investigated. The results indicate that different structures have a very important influence on their properties. The structure–activity relationship of silver cluster materials provides positive guidance for further design and synthesis of functional silver cluster materials. |
| Databáze: | OpenAIRE |
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